Energy, Environmental, and Catalysis Applications
- Hengji Zhu
Hengji Zhu
Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, PR China
More by Hengji Zhu
- Tangchao Xie
Tangchao Xie
Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, PR China
More by Tangchao Xie
- Bin Liang
Bin Liang
Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, PR China
More by Bin Liang
- Zheping Lin
Zheping Lin
Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, PR China
More by Zheping Lin
- Weitao Zheng
Weitao Zheng
Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, PR China
More by Weitao Zheng
- Jialang He
Jialang He
Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, PR China
See AlsoFullerol Initiates Stem Cell–Nanomaterials Interactions for Enhanced Tissue Regeneration via Clathrin-Mediated Endocytosis and Nuclear Factor Erythroid 2-Related Factor 2 SignalingPoly-T-Modified Gold Nanorods Suppress Macrophage-Mediated Inflammation for Periodontitis TherapyMetal-Doped CoS Nanosheets: Breaking Scaling Limitations for Enhanced Urea Electrooxidation and Hydrogen EvolutionMore by Jialang He
- Shiyun Xiong
Shiyun Xiong
Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, PR China
More by Shiyun Xiong
- Yijuan Li*
Yijuan Li
Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, PR China
*Email: [emailprotected]
More by Yijuan Li
- Shaoming Huang*
Shaoming Huang
School of Chemistry and Materials Science, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou 310024, PR China
*Email: [emailprotected]
More by Shaoming Huang
Other Access OptionsSupporting Information (1)
ACS Applied Materials & Interfaces
Cite this: ACS Appl. Mater. Interfaces 2025, XXXX, XXX, XXX-XXX
Click to copy citationCitation copied!
https://pubs.acs.org/doi/10.1021/acsami.5c03058
Published April 16, 2025
Publication History
Received
Accepted
Revised
Published
online
research-article
© 2025 American Chemical Society
Request reuse permissions
Abstract
Click to copy section linkSection link copied!
The lithium metal anode (LMA) offers high theoretical capacity and low electrochemical potential but faces challenges including uncontrolled dendrite growth, unstable solid electrolyte interphase (SEI), and infinite volume expansion. This study designs and constructs a nitrogen-doped hollow nanocubic carbon with an inside-out lithiophilic gradient (Co/ZnO-HNC) as the LMA host. On one hand, the inside-out gradient-lithiophilic ZnO and Co sites enable lithium nucleation and growth from the interior to exterior of the hollow carbon nanocube, inducing the dendrite-free Li plating/stripping. On the other hand, the hollow nanocubic structure provides confined space for Li storage and buffers the volume change of Li during cycling. Consequently, the Co/ZnO-HNC electrode exhibits an ultralow nucleation overpotential (3.7 mV) at 1 mA cm–2 and cycles stably for 300 times with an average Coulombic efficiency of 98.8% in half-cells. When matched with a commercial LiFePO4 cathode (20 mg cm–2), the full cell retains a 91.9% capacity retention over 200 cycles at 1 C with a high reversible capacity of 133.8 mAh g–1. Therefore, this work provides a scalable and effective strategy for designing gradient-lithiophilic frameworks to achieve high-performance lithium metal batteries.
ACS Publications
© 2025 American Chemical Society
Subjects
what are subjects
Article subjects are automatically applied from the ACS Subject Taxonomy and describe the scientific concepts and themes of the article.
- Deposition
- Electrical properties
- Electrochemical cells
- Electrodes
- Lithium
Keywords
what are keywords
Article keywords are supplied by the authors and highlight key terms and topics of the paper.
Read this article
To access this article, please review the available access options below.
Get instant access
Purchase Access
Read this article for 48 hours. Check out below using your ACS ID or as a guest.
Recommended
Access through Your Institution
You may have access to this article through your institution.
Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.
Recommended
Log in to Access
You may have access to this article with your ACS ID if you have previously purchased it or have ACS member benefits. Log in below.
-
Purchase access
Purchase this article for 48 hours $48.00 Add to cart Purchase this article for 48 hours Checkout
Cited By
Click to copy section linkSection link copied!
This article has not yet been cited by other publications.
Download PDF
Get e-Alerts
Get e-Alerts
ACS Applied Materials & Interfaces
Cite this: ACS Appl. Mater. Interfaces 2025, XXXX, XXX, XXX-XXX
Click to copy citationCitation copied!
Published April 16, 2025
Publication History
Received
Accepted
Revised
Published
online
© 2025 American Chemical Society
Request reuse permissions
Article Views
70
Altmetric
-
Citations
-
Learn about these metrics
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.
